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Skin

How to exfoliate without damaging your skin barrier

The studies that left the barrier intact and the ones that broke it apart differ mostly in strength and how long the acid stayed on.

By Scara Kang · · 6 min read

In short

To exfoliate without damaging your skin barrier, keep acids low in strength and frequency. In studies, 4% glycolic acid twice daily left the barrier intact, while 12% for an hour daily raised water loss and redness. Gentler acids such as gluconolactone (a PHA) irritate less, and daily sunscreen matters while you use any AHA.

You started an acid toner for rough texture, and for the first week your skin looked smoother. By the third week, your usual moisturizer stings when it goes on, your cheeks look shiny but feel tight, and the redness around your nose has not faded by evening. That is the point where many people ask how to exfoliate without damaging your skin barrier, and the answer from the research is less about which acid you use than about how much, how strong and how often.

Can exfoliating damage your skin barrier?

It can, at high strengths and long contact times. At low strengths, the barrier held up.

The clearest comparison comes from two small European studies of glycolic acid, the most common alpha hydroxy acid (AHA). In a German study, volunteers applied a 4% glycolic acid formula to the forearm twice a day for 3 weeks. Water loss through the skin did not change, and electron microscopy showed the acid loosened only the outermost, already-shedding layer. The authors concluded that “the barrier structures of the SC are not disrupted by glycolic acid formulations at the concentration used”, SC being the stratum corneum, the skin’s outer layer.

A different picture came from 12% glycolic acid left on for 60 minutes once a day, 5 days a week, for 2 weeks, in 6 volunteers. Water loss through the skin rose significantly, skin hydration dropped between days 11 and 18, and the acid “rapidly induced an intense erythema”, the medical term for redness. Unlike the prescription retinoid it was compared with, the rise in water loss did not persist after stopping.

So the same acid can be harmless or harsh. The difference was the dose and the exposure time.

What strength and pH are gentle enough?

For leave-on products, lower than 10% and not too acidic. A 2010 review by researchers from the US Food and Drug Administration and the National Institutes of Health summarizes the limits recommended by the US Cosmetic Ingredient Review (CIR) expert panel: “the CIR Panel recommended limitations on the concentration of αHAs (<10%) and the pH (at or above 3.5) of cosmetic products containing αHAs.”

The pH matters because a lower number means a more acidic product, and the panel set a floor for it alongside the strength limit.

Which exfoliant is gentlest on the skin barrier?

Polyhydroxy acids (PHAs) such as gluconolactone have the best tolerance data, with a caveat about who ran the studies.

In an Italian study, 11 adults applied four different acids at 8% to their forearms twice daily for 4 weeks. None of them changed water loss or redness by week 4. But when the researchers then challenged the skin with an irritating detergent, the sites treated with gluconolactone lost significantly less water than untreated skin and than the glycolic acid site.

A 12-week facial study compared a gluconolactone regimen with a glycolic acid regimen. The AHA did slightly more for sallowness, 17.1% improvement against 12.4%, but stinging and burning were significantly worse with the AHA at weeks 6 and 12, and the authors reported that “the PHA regimen was better tolerated than the AHA regimen.” The authors worked for NeoStrata, a company that sells both PHA and AHA products.

Our Ingredient A–Z entries on PHA and glycolic acid cover each acid on its own.

Does exfoliating make your skin sensitive to the sun?

Glycolic acid does, temporarily. In a randomized, double-blind US study, 29 adults applied 10% glycolic acid at pH 3.5 or a placebo to their backs 6 days a week for 4 weeks. The glycolic acid sites then burned more easily under UV light and formed more sunburn cells. The authors concluded: “Short-term application of 10% glycolic acid sensitizes the skin to the damaging effects of UV light. This photosensitivity is reversed within a week of terminating treatments.”

A later FDA-led study in 14 people tested 10% glycolic acid and 2% salicylic acid (a BHA) side by side for 3.5 weeks. Glycolic acid increased redness, DNA damage and sunburn cells after simulated sunlight; salicylic acid did not produce significant changes.

So if you use an AHA, daily sunscreen is part of using it, not an optional extra.

How often should you exfoliate your face?

Less often than the bottle may suggest at first. No study we know of sets one ideal frequency for everyone, so we use the pattern above. The barrier stayed intact with a low strength, and broke down with a high strength used daily. Start once or twice a week with a low-strength product, and add a night only if your skin still feels comfortable a few days later.

If you also use a retinoid, keep it and the acid on separate nights. Skin cycling is one simple way to schedule that. In winter, when skin often reacts more easily, it can help to cut back; our guide to why skin gets more sensitive in winter explains why.

What are the signs you have over-exfoliated?

The reactions measured in the studies above are the ones to watch for: redness that does not fade, stinging or burning from products that used to feel neutral, and skin that feels tight or dry even after moisturizer. If you notice them, stop all exfoliants and keep to a gentle cleanser, moisturizer and sunscreen until your skin feels normal again, then restart at a lower frequency.

How do you exfoliate without damaging your skin barrier?

  • Choose one exfoliant. An AHA, a BHA or a PHA, not all three at once.
  • Start low. Under 10% for a leave-on AHA, at a pH of 3.5 or higher, or a PHA if your skin reacts easily.
  • Start slow. Once or twice a week, on clean, dry skin.
  • Moisturize after. Apply a moisturizer on top to help your skin hold water.
  • Wear sunscreen every morning while you use an AHA, and for at least a week after you stop.
  • Patch test first if your skin is reactive; our patch test guide shows how.

The same rules apply below the neck, with a few differences; see how to exfoliate your body without irritation.

Editor’s note

I have used a pharmacy AHA/BHA product once a week for years, and I still keep it to once a week, on top of oil and balm deep cleansing twice a week. I have also used haruharu wonder’s Centella 3% PHA serum. The clearest layering lesson I have came from brightening products rather than acids: when I once stacked several melanin-care products at once, my skin answered with dry patches and roughness.

This article is for general cosmetic information and is not medical advice. If redness or stinging lasts after you stop exfoliating, see a dermatologist.

Evidence: The guidance rests on small human studies of glycolic acid, gluconolactone and salicylic acid, most with 6 to 29 people, plus safety limits set by the US Cosmetic Ingredient Review panel; there are no large trials of exfoliating schedules.

If you want to try it
  1. haruharu wonder: Centella 3% PHA Gentle Liquid Exfoliating Serum
FAQ

What are the signs of over-exfoliation?

Stinging when you apply products that never used to sting, redness that lingers, and skin that feels tight or dry even after moisturizer. In studies, these were the reactions to high-strength glycolic acid: redness, lower skin hydration and more water loss through the skin.

How often should you exfoliate your face?

There is no study that sets one right number. A cautious start is once or twice a week with a low-strength product, increasing only if your skin stays comfortable. If you use a retinoid, keep acids on different nights.

Is PHA gentler than AHA?

Yes, in the studies available. In a 12-week facial study, a gluconolactone (PHA) regimen caused less stinging and burning than a glycolic acid (AHA) regimen. That study was run by a company that sells both kinds of product.

Does exfoliating make your skin more sensitive to the sun?

Glycolic acid does. In a US study, 4 weeks of 10% glycolic acid made skin burn more easily under UV light, and the effect was gone within a week of stopping. In a similar study, 2% salicylic acid did not have that effect. Wear sunscreen every day while you use an AHA.

References
  1. Fartasch M, Teal J, Menon GK. Mode of action of glycolic acid on human stratum corneum: ultrastructural and functional evaluation of the epidermal barrier. Arch Dermatol Res. 1997;289(7):404-9.
  2. Effendy I, et al. Functional changes in human stratum corneum induced by topical glycolic acid: comparison with all-trans retinoic acid. Acta Derm Venereol. 1995;75(6):455-8.
  3. Kaidbey K, et al. Topical glycolic acid enhances photodamage by ultraviolet light. Photodermatol Photoimmunol Photomed. 2003;19(1):21-7.
  4. Kornhauser A, et al. The effects of topically applied glycolic acid and salicylic acid on ultraviolet radiation-induced erythema, DNA damage and sunburn cell formation in human skin. J Dermatol Sci. 2009;55(1):10-7.
  5. Kornhauser A, Coelho SG, Hearing VJ. Applications of hydroxy acids: classification, mechanisms, and photoactivity. Clin Cosmet Investig Dermatol. 2010;3:135-42.
  6. Berardesca E, et al. Alpha hydroxyacids modulate stratum corneum barrier function. Br J Dermatol. 1997;137(6):934-8.
  7. Edison BL, et al. A polyhydroxy acid skin care regimen provides antiaging effects comparable to an alpha-hydroxyacid regimen. Cutis. 2004;73(2 Suppl):14-7.

Editorial content, not medical advice.

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